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metal accumulation and phytostabilization potential of dominant plant species growing on manganese minetailings

YANG Shengxiang,LIANG Shichu,YI Langbo,XU Bibo,CAO Jianbing,GUO Yifeng,ZHOU Yu

《环境科学与工程前沿（英文）》 2014年第8卷第3期页码 394-404 doi: 10.1007/s11783-013-0602-4

摘要： Screening plants that are hypertolerant to and excluders of certain heavy metals plays a fundamental role in a remediation strategy for metalliferous mine tailings. A field survey of terrestrial higher plants growing on Mn mine tailings at Huayuan, Hunan Province, China was conducted to identify candidate species for application in phytostabilization of the tailings in this region. In total, 51 species belonging to 21 families were recorded and the 12 dominant plants were investigated for their potential in phytostabilization of heavy metals. Eight plant species, , , , , , , , and accumulated much lower concentrations of heavy metals in shoots and roots than the associated soils and bioconcentration factors (BFs) for Cd, Mn, Pb and Zn were all<1, demonstrating a high tolerance to heavy metals and poor metals translocation ability. The field investigation also found that these species grew fast, accumulated biomass rapidly and developed a vegetation cover in a relatively short time. Therefore, they are good candidates for phytostabilization purposes and could be used as pioneer species in phytoremediation of Mn mine tailings in this region of South China.

关键词： Mn mine tailings heavy metal accumulation phytostabilization

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金属矿山尾矿问题及其综合利用与治理

蔡嗣经,杨鹏

《中国工程科学》 2000年第2卷第4期页码 89-92

摘要：

我国金属矿山在地面积存的尾矿已达40多亿t，并以每年约2.1亿t的速度在增长。金属矿山尾矿的主要特点为颗粒极细、数量极大、毒性很强、浓度很低。尾矿库占用大量土地，尾矿库工程事故，尾矿对地面环境和地下水源的污染等，迫切需要采用新技术开展对尾矿综合利用和治理的研究与开发，包括回收利用尾矿中的金属和非金属元素，利用尾矿制作建筑材料或磁性肥料；采用各种措施全面治理尾矿，如设立地下尾矿库，利用地面尾矿库作排土场，尾矿膏体地面无坝堆放与同步复垦等，其最终目标是建立“无尾矿山”。

关键词：金属矿山尾矿环境污染地下尾矿库尾矿膏体无尾矿

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Nutrient status and pollution levels in five areas around a manganese mine in southern China

Kehui Liu, Xiaolu Liang, Chunming Li, Fangming Yu, Yi Li

《环境科学与工程前沿（英文）》 2020年第14卷第6期 doi: 10.1007/s11783-020-1279-0

摘要： Abstract • The soil TP level was high or extremely high in all areas. • TN, OM and available Cu were insufficient in EA, TA and RA. • All areas reached the heavily polluted level and had high ecological risk levels. • Mn and Cd were the dominant pollutants. Nutrient status and pollution levels are the main factors affecting soil restoration. The nutrient status and pollution levels in five areas, an unexplored mine area (UA), an explored mine area (EA), a tailings area (TA), a reclamation area (RA) and an agricultural area (AA), around the Pingle manganese mine in Guangxi, China, were assessed in this study. The results showed that the average total phosphorus in these five areas ranged from 1.05 to 1.57 mg/kg, corresponding to grades of extremely high and high. The average total nitrogen values were 0.19, 0.69, 0.93, 1.24 and 1.67 mg/kg in EA, TA, RA, UA and AA, corresponding to grades of very low, low, medium-low, medium-high and medium-high, respectively. The average organic matter values were 12.78, 8.92, 22.77, 21.29 and 29.11 mg/kg in EA, TA, RA, UA and AA, which corresponded to grades of medium-low, low, medium-high, medium-high and medium-high, respectively. All these results indicated that the total phosphorus was sufficient in these areas, while the total nitrogen and organic matter were insufficient in EA, TA and RA. The available concentrations of Mn and Zn corresponded to the intermediate grade, while the values for Cu corresponded to the very low grade; these might be another factor restricting ecological reclamation. Contamination and ecological risk assessments based on the single contamination index, Nemerow multi-factor index and potential ecological risk index showed that the five tested areas around the Mn mine were considered heavily polluted and presented high ecological risk. Mn and Cd were the dominant pollutants.

关键词： Ecological reclamation Ecological risk assessment Heavy metal Mn mine Soil nutrients

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Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive

Chengyuan SU,Weiguang LI,Xingzhe LIU,Xiaofei HUANG,Xiaodan YU

《环境科学与工程前沿（英文）》 2016年第10卷第1期页码 37-45 doi: 10.1007/s11783-014-0729-y

摘要： A study of the decolorization of reactive brilliant blue in an aqueous solution using Fe-Mn-sepiolite as a heterogeneous Fenton-like catalyst has been performed. The Fourier transform infrared (FTIR) spectra of the catalyst showed bending vibrations of the Fe-O. The X-ray diffraction (XRD) patterns of the catalyst showed characteristic diffraction peaks of α-Fe O , γ-Fe O and MnO. A four factor central composite design (CCD) coupled with response surface methodology (RSM) was applied to evaluate and optimize the important variables (catalyst addition, hydrogen peroxide dosage, initial pH value and initial dye concentration). When the reaction conditions were catalyst dosage= 0.4 g, [H O ]= 0.3 mL, pH= 2.5, [reactive brilliant blue] = 50 mg·L , and volume of solution= 500 mL at room temperature, the decolorization efficiency of reactive brilliant blue was 91.98% within 60 min. Moreover, the Fe-Mn-sepiolite catalyst had good stability for the degradation of reactive brilliant blue even after six cycles. Leaching of iron ions (<0.4 mg·L ) was observed. The decoloring process was reactive brilliant blue specific via a redox reaction. The benzene ring and naphthalene ring were first oxidized to open ring; these were then oxidized to the alcohol and carboxylic acid. The reactive brilliant blue was decomposed mainly by the attack of ·OH radicals including surface-bound ·OH radicals generated on the catalyst surface.

关键词： Fe-Mn-sepiolite catalyst heterogeneous Fenton-like reactive brilliant blue homogeneous precipitation method hydroxyl radical

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Denitrification performance and sulfur resistance mechanism of Sm–Mn catalyst for low temperature NH-SCR

《化学科学与工程前沿（英文）》 2023年第17卷第5期页码 617-633 doi: 10.1007/s11705-022-2258-8

摘要： MnO_x and Sm–Mn catalysts were prepared with the coprecipitation method, and they showed excellent activities and sulfur resistances for the selective catalytic reduction of NO_x by NH₃ between 50 and 300 °C in the presence of excess oxygen. 0.10Sm–Mn catalyst indicated better catalytic activity and sulfur resistance. Additionally, the Sm doping led to multi-aspect impacts on the phases, morphology structures, gas adsorption, reactions process, and specific surface areas. Therefore, it significantly enhances the NO conversion, N₂ selectivity, and sulfur resistance. Based on various experimental characterization results, the reaction mechanism of catalysts and the effect of SO₂ on the reaction process about the catalysts were extensively explored. For 0.10Sm–Mn catalyst, manganese sulfate and sulfur ammonium cannot be generated broadly under the influence of SO₂ and the amount of surface adsorbed oxygen. The Bronsted acid sites strengthen significantly due to the addition of SO₂, enhancing the sulfur resistance of the 0.10Sm–Mn catalyst.

关键词： MnO_x Sm–Mn catalyst NH₃-SCR sulfur resistance

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矿山安全减灾系统科学——矿山灾害学

周利华

《中国工程科学》 2003年第5卷第7期页码 90-94

摘要：

矿山灾害学是一门综合性强并需不断扩充的矿山安全减灾科学。它与以往单一矿山灾害防治理论研究相比，具有综合性、预测性和经济性三大特征；它的安全减灾原理包含了安全哲学、安全经济学等八大原理；它的研究模型体现了宏观与微观相统一的原则。因此，矿山灾害学的研究，应以科学的系统论思想为指导，采用逻辑与历史相统一法，既要从微观上研究矿山灾害中单一灾种事故的防治技术和方法，又要在宏观上从不同学科、不同层次、不同的方位切入，对矿山灾害进行系统的研究；与此同时，还必须大力开展多层次、多领域、多方位的国际协作。

关键词：矿山灾害矿山安全矿山灾害学

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Digital Mine Research and Practice Based on Mining and Metallurgy System Engineering

An-lin Shao

《工程管理前沿（英文）》 2016年第3卷第1期页码 67-73 doi: 10.15302/J-FEM-2016006

摘要： Iron ore is necessarily basic raw material for industrialization and urbanization and related to the industrial distribution and development programming. The lean iron ore resource in our country is high-cost and low-efficiency, which cannot meet the demand of iron and steel industry, and even endanger the safety of industrial economy. Ansteel mining has created “grade decision-based multi-system integration” mode of mining and metallurgy system engineering and realized scale and efficient development of lean iron ore on basis of the construction of digital mines. Moreover, the “wisdom mines” was proposed and had led to the transformation and upgrading of iron developments.

关键词： exploration of lean iron ore mining and metallurgy system engineering digital mine wisdom mine

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CO₂ methanation and co-methanation of CO and CO₂ over Mn-promoted Ni/Al₂

Kechao Zhao,Zhenhua Li,Li Bian

《化学科学与工程前沿（英文）》 2016年第10卷第2期页码 273-280 doi: 10.1007/s11705-016-1563-5

摘要： A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

关键词： Mn promotion nickel catalysts CO₂ methanation co-methanation of CO and CO₂

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Comparing the adsorption behaviors of Cd, Cu and Pb from water onto Fe-Mn binary oxide, MnO

Wei XU,Huachun LAN,Hongjie WANG,Hongming LIU,Jiuhui QU

《环境科学与工程前沿（英文）》 2015年第9卷第3期页码 385-393 doi: 10.1007/s11783-014-0648-y

摘要： The adsorption potential of FMBO, FeOOH, MnO for the removal of Cd , Cu and Pb in aqueous systems was investigated in this study. Comparing to FMBO and FeOOH, MnO offered a much higher removal capacity towards the three metal ions. The maximal adsorption capacity of MnO for Cd , Cu and Pb were 1.23, 2.25 and 2.60 mmol·g , respectively. And that for FMBO were 0.37, 1.13, and 1.18 mmol·g and for FeOOH were 0.11, 0.86 and 0.48 mmol·g , respectively. The adsorption behaviors of the three metal ions on the three adsorbents were all significantly affected by pH values and heavy metal removal efficiency increased with pH increased. The Langmuir and Freundlich adsorption models were used to describe the adsorption equilibrium of the three metal ions onto the three adsorbents. Results showed that the adsorption equilibrium data fitted well to Langmuir isotherm and this indicated that adsorption of metal ions occurred on the three metal oxides adsorbents limited to the formation of a monolayer. More negative charged of MnO surface than that of FMBO and FeOOH could be ascribed by lower pH of MnO than that of FMBO and FeOOH and this could contribute to more binding sites on MnO surface than that of FMBO and FeOOH. The higher metal ions uptake by MnO than FMBO and FeOOH could be well explained by the surface charge mechanism.

关键词： heavy metals Fe-Mn binary oxide manganese dioxide ferric hydroxide adsorption

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Visible light induces bacteria to produce superoxide for manganese oxidation

《环境科学与工程前沿（英文）》 2023年第17卷第2期 doi: 10.1007/s11783-023-1619-y

摘要：

● Term of manganese-oxidizing microorganisms should be reconsidered.

关键词： Mn(II) oxidation Manganese-oxidizing bacteria Reactive oxygen species Mn(III/IV) oxides

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Microwave-assisted catalytic oxidation of gaseous toluene with a Cu-Mn-Ce/cordierite honeycomb catalyst

Longli Bo, Shaoyuan Sun

《化学科学与工程前沿（英文）》 2019年第13卷第2期页码 385-392 doi: 10.1007/s11705-018-1738-3

摘要： A novel Cu-Mn-Ce/cordierite honeycomb catalyst was prepared by an incipient wetness method and the catalyst was characterized. The active ingredients were present as various spinel species of Cu, Mn and Ce oxides with different valences and they were unevenly dispersed over the surface of the catalyst. The catalytic oxidation of gaseous toluene was primarily investigated using a fixed bed reactor under microwave heating in the continuous flow mode. Under the optimal conditions of 6.7 wt-% loading of the active component, a bed temperature of 200°C, a flow rate of 0.12 m ·h and an initial concentration of toluene of 1000 mg·m , the removal and mineralization efficiencies of toluene were 98% and 70%, respectively. Thus the use of the microwave effectively improved the oxidation of toluene and this is attributed to dipole polarization and hotspot effects. After four consecutive cycles (a total of 1980 min), the Cu-Mn-Ce/cordierite catalyst still exhibited excellent catalytic activity and structural stability, and the toluene removal was higher than 90%. This work demonstrates the possibility of treating volatile organic compounds in exhaust gases by microwave-assisted catalytic oxidation.

关键词： microwave catalytic oxidation toluene Cu-Mn-Ce/cordierite mineralization

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Fluoride ions adsorption from water by CaCO enhanced Mn–Fe mixed metal oxides

《化学科学与工程前沿（英文）》 2023年第17卷第2期页码 236-248 doi: 10.1007/s11705-022-2193-8

摘要： Novel CaCO₃-enhanced Mn–Fe mixed metal oxides (CMFC) were successfully prepared for the first time by a simple-green hydrothermal strategy without any surfactant or template combined with calcination process. These oxides were then employed as an adsorbent for adsorptive removal of excess fluoride ions. The adsorbent was characterized by SEM, XPS, XRD, FTIR, and BET analysis techniques. The adsorption property of CMFC toward fluoride ion was analyzed by batch experiments. In fact, CMFC exhibited adsorption capacity of 227.3 mg∙g^‒1 toward fluoride ion. Results showed that ion exchange, electrostatic attraction and chemical adsorption were the main mechanism for the adhesion of large amount of fluoride ion on the CMFC surface, and the high adsorption capacity responded to the low pH of the adsorption system. When the fluoride ion concentration was increased from 20 to 200 mg∙L^‒1, Langmuir model was more in line with experimental results. The change of fluoride ion adsorption with respect to time was accurately described by pseudo-second-order kinetics. After five cycles of use, the adsorbent still maintains a performance of 70.6% of efficiency, compared to the fresh adsorbent. Therefore, this material may act as a potential candidate for adsorbent with broad range of application prospects.

关键词： mesoporous materials metal oxides fluoride ion adsorption mechanism

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Study on a green synthetic method of TRPPMCl (M= Fe, Mn, Co)

Jing FAN, Yuanbin SHE, Aixin WANG

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 222-223 doi: 10.1007/s11705-009-0059-y

摘要： A green synthetic method using mixted solvents of di-methyl formamide(DMF) and acids instead of single DMF to synthesize metalloporphyrins(TRPPMCl) from TRPPH and MCl metallization was proposed in this paper. A series of TRPPMCl (M= Fe, Mn, Co) were synthesized through this innovative synthetic method, and these complexes were characterized with various spectroscopic techniques, including IR and UV-Vis spectroscopy. The results showed that the metallization time was markedly reduced from about 10 h to 0.5 h in contrast with the conventional synthetic methods.

关键词： TRPPMCl metalloporphyrins green synthesis acid

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尾矿坝溃决的剖析与未来的警示

Jane Palmer

《工程（英文）》 2019年第5卷第4期页码 605-606 doi: 10.1016/j.eng.2019.07.009

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Effect of K and Ca on catalytic activity of Mn-CeO

Boxiong SHEN, Lidan DENG, Jianhong CHEN

《环境科学与工程前沿（英文）》 2013年第7卷第4期页码 512-517 doi: 10.1007/s11783-013-0519-y

摘要： Mn-CeO /Ti-pillared clay (PILC) is an attractive catalyst for selective catalytic reduction of NO at low temperature because of its low cost. The poisoning of K and Ca on the catalyst of Mn-CeO /Ti-PILC is an important problem because K and Ca are always in presence in flue gas. To investigate the effect of K and Ca on the physicochemical characters of the catalysts, the techniques of NH -temperature programmed desorption (TPD), H -temperature programmed reduction (TPR), and X-ray photoelectron spectroscopy (XPS) were used to analyze the fresh and deactivated catalysts of Mn-CeO /Ti-PILC. (Ca)Mn-CeO /Ti-PILC and (K)Mn-CeO /Ti-PILC are denoted for the dopes of the catalyst of Mn-CeO /Ti-PILC with Ca and K, respectively. The activities of Mn-CeO /Ti-PILC, (Ca)Mn-CeO /Ti-PILC and (K)Mn-CeO /Ti-PILC for NH -selective catalytic reduction (SCR) reaction at low temperature were investigated. The results showed that with the dopes of K and Ca on the catalysts, the SCR activities of the catalysts decreased greatly, and K exhibited more poisoning effect than Ca. With the dopes of K and Ca, the acidity, the redox property and chemisorbed oxygen on the surfaces of the catalysts were decreased, which resulted in a decreasing in SCR activity.

关键词： Mn-CeO_x/Ti-pillared clay (PILC) low-temperature selective catalytic reduction (SCR) K and Ca poisoning effect